by BDanielMayfield » Mon Apr 22, 2019 2:58 pm
Chris Peterson wrote: ↑Mon Apr 22, 2019 1:31 pm
BDanielMayfield wrote: ↑Mon Apr 22, 2019 1:27 pm
My hunch is that sporadic methane on Mars is from a non biological source.
Probably true. But still an intriguing mystery.
It's nice when divergent thinkers are drawn toward the same thoughts.
Some salient info on possible non-biologic methane production, from wikipedia's Methane article:
The two main routes for geological methane generation are (i) organic (thermally generated, or thermogenic) and (ii) inorganic (abiotic)[28]. ... The more important source of methane at depth (crystalline bedrock) is abiotic. Abiotic means that the methane formation took place involving inorganic compounds, without biological activity, either through magmatic processes or via water-rock reactions that occur at low temperatures and pressures, like serpentinization.[29][30]
And from wiki's article on serpentinite:
Serpentinite is a rock composed of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake.[1] Minerals in this group, which are rich in magnesium and water, light to dark green, greasy looking and slippery feeling, are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle. The mineral alteration is particularly important at the sea floor at tectonic plate boundaries.[2]
...
Serpentinization is a geological low-temperature metamorphic process involving heat and water in which low-silica mafic and ultramafic rocks are oxidized (anaerobic oxidation of Fe2+ by the protons of water leading to the formation of H2) and hydrolyzed with water into serpentinite. Peridotite, including dunite, at and near the seafloor and in mountain belts is converted to serpentine, brucite, magnetite, and other minerals — some rare, such as awaruite (Ni3Fe), and even native iron. In the process large amounts of water are absorbed into the rock increasing the volume, reducing the density and destroying the structure.[3]
The density changes from 3.3 to 2.7 g/cm3 with a concurrent volume increase on the order of 30-40%. The reaction is highly exothermic and rock temperatures can be raised by about 260 °C (500 °F),[3] providing an energy source for formation of non-volcanic hydrothermal vents. The magnetite-forming chemical reactions produce hydrogen gas under anaerobic conditions prevailing deep in the mantle, far from the Earth's atmosphere. Carbonates and sulfates are subsequently reduced by hydrogen and form methane and hydrogen sulfide. The hydrogen, methane, and hydrogen sulfide provide energy sources for deep sea chemotroph microorganisms.[3]
...
Abiotic methane production on Mars by serpentinization
The presence of traces of methane in the atmosphere of Mars has been hypothesized to be a possible evidence for life on Mars if methane was produced by bacterial activity. Serpentinization has been proposed as an alternative non-biological source for the observed methane traces.[7][8]
[quote="Chris Peterson" post_id=291672 time=1555939909 user_id=117706]
[quote=BDanielMayfield post_id=291671 time=1555939640 user_id=139536]
My hunch is that sporadic methane on Mars is from a non biological source.
[/quote]
Probably true. But still an intriguing mystery.
[/quote]
It's nice when divergent thinkers are drawn toward the same thoughts.
Some salient info on possible non-biologic methane production, from wikipedia's Methane article:
[quote]The two main routes for geological methane generation are (i) organic (thermally generated, or thermogenic) and (ii) inorganic (abiotic)[28]. ... The more important source of methane at depth (crystalline bedrock) is abiotic. Abiotic means that the methane formation took place involving inorganic compounds, without biological activity, either through magmatic processes or via water-rock reactions that occur at low temperatures and pressures, like serpentinization.[29][30][/quote]
And from wiki's article on serpentinite:
[quote]Serpentinite is a rock composed of one or more serpentine group minerals, the name originating from the similarity of the texture of the rock to that of the skin of a snake.[1] Minerals in this group, which are rich in magnesium and water, light to dark green, greasy looking and slippery feeling, are formed by serpentinization, a hydration and metamorphic transformation of ultramafic rock from the Earth's mantle. The mineral alteration is particularly important at the sea floor at tectonic plate boundaries.[2]
...
Serpentinization is a geological low-temperature metamorphic process involving heat and water in which low-silica mafic and ultramafic rocks are oxidized (anaerobic oxidation of Fe2+ by the protons of water leading to the formation of H2) and hydrolyzed with water into serpentinite. Peridotite, including dunite, at and near the seafloor and in mountain belts is converted to serpentine, brucite, magnetite, and other minerals — some rare, such as awaruite (Ni3Fe), and even native iron. In the process large amounts of water are absorbed into the rock increasing the volume, reducing the density and destroying the structure.[3]
The density changes from 3.3 to 2.7 g/cm3 with a concurrent volume increase on the order of 30-40%. The reaction is highly exothermic and rock temperatures can be raised by about 260 °C (500 °F),[3] providing an energy source for formation of non-volcanic hydrothermal vents. The magnetite-forming chemical reactions produce hydrogen gas under anaerobic conditions prevailing deep in the mantle, far from the Earth's atmosphere. Carbonates and sulfates are subsequently reduced by hydrogen and form methane and hydrogen sulfide. The hydrogen, methane, and hydrogen sulfide provide energy sources for deep sea chemotroph microorganisms.[3]
...
Abiotic methane production on Mars by serpentinization
The presence of traces of methane in the atmosphere of Mars has been hypothesized to be a possible evidence for life on Mars if methane was produced by bacterial activity. Serpentinization has been proposed as an alternative non-biological source for the observed methane traces.[7][8][/quote]